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Rhodium

Product
(2,4-pentanedionato)carbonyl(triphenylphosphino)rhodium(I)
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Rh-43, ROPAC, acetylacetonatocarbonyl(triphenylphosphine)rhodium(I)

(2,4-pentanedionato)carbonyl(triphenylphosphino)rhodium(I)

Chemical Formula

Rh(CO)(PPh3)(acac)

 

Product Codes

UK: 207000

This product can be ordered worldwide under the above product codes

 

CAS number

25470-96-6

 

Product Family

Pgm compound (solid)

 

Process

Hydroformylation

 

Market

Chemicals

 

Benefits
ROPAC is air stable, contains no halide and has good solubility in organic solvents. It has a higher rhodium content than Rh-42. It has been used for hydroformylation since the development of the low pressure oxo process in the 1970’s.

Rh-43 Ropac 

Application

ROPAC catalyses hydroformylation reactions. It is normally used with... 


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(2,4-pentanedionato)dicarbonyl rhodium
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Rh-50, rhodium coacac, Acetylacetonatocarbonyl rhodium

(2,4-pentanedionato)dicarbonyl rhodium

Chemical Formula

Rh(acetylacetonate)(CO)2

 

Product Codes

UK: 209050
US: C3022

This product can be ordered worldwide under the above product codes

 

CAS number

14874-82-9

 

Product Family

Pgm compound (solid)

 

Process

Hydroformylation

 

Market

Chemicals

 

Benefits
Rh-50 is air stable, contains no halide and has good solubility in organic solvents. It has a higher rhodium content than ROPAC.

 

(2,4-pentanedionato) dicarbonyl rhodium(I)


Application
Rh-50 catalyses hydroformylation reactions. It is sometimes used with ligands such as triphenylphosphine. It is more hazardous than...


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Hexakis(acetato)triaquo-µ-oxotrirhodium(III) acetate solution, rhodium acetate brown solution
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Rh-112, rhodium acetate brown, rhodium(III) acetate

Hexakis(acetato)triaquo-µ-oxotrirhodium(III) acetate solution, rhodium acetate brown solution

Chemical Formula

[Rh3(OAc)63?O(H2O)3]OAc

 

Product Codes

UK: 204001
US: C3043

This product can be ordered worldwide under the above product codes

 

CAS number

42204-14-8

 

Product Family

Pgm compound solution (organic)

 

Process

Hydroformylation, Carbonylation

 

Market

Chemicals

 

Benefits
Rh-112 solution is air stable and contains no halide.
 
 
Rhodium acetate brown
 
Application
Rh-112 solution is a catalyst precursor for hydroformylation reactions.  It is sometimes used with ligands such as triphenylphosphine. It is supplied in solution containing...


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Tetrakis(acetato)dirhodium(II)
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Rh-110, rhodium acetate green, rhodium(II) acetate

Tetrakis(acetato)dirhodium(II)

Chemical Formula

[Rh2(CH3COO)4]

 

Product Codes

US: C3041

This product can be ordered worldwide under the above product codes

 

CAS number

15956-28-2

 

Product Family

Pgm compound (solid)

 

Process

Coupling

 

Market

Chemicals

 

Benefits
The product is an air-stable solid that is water soluble but with limited solubility in most organic solvents.

 

Rhodium acetate dimer

 

Application
Rhodium(II) acetate dimer is used as a homogeneous catalyst for a variety of organic transformations, such as Cyclopropanation, Aromatic cycloaddition, C-H insertion, Oxidation of alcohols and X-H insertion (X = N/S/O).

Shipping & Handling
Please refer to the relevant Safety Data Sheet for further information.


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Rhodium nitrate
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Rhodium nitrate

Rhodium nitrate

Chemical Formula

Rh(NO3)3

 

Product Codes

UK: 200001
US: C3013
CN: FM01RH0005

This product can be ordered worldwide under the above product codes

 

CAS number

10139-58-9

 

Product Family

Pgm compound solution (aqueous)

 

Process

Catalyst manufacturing

 

Market

Automotive

 

Benefits 
The solution contains 5 – 20% nitric acid to prevent hydrolysis and ensure stability.
Rhodium nitrate solution is air stable and has a low halide content.
 
Application 
Rhodium nitrate solution is used as a precursor to make heterogeneous (supported) catalysts.
 
Shipping & Handling

Rhodium nitrate solution is harmful if swallowed and causes...

 

 


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Rhodium chloride solution
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Rhodium chloride solution

Rhodium chloride solution

Chemical Formula

H3[RhCl6]

 

Product Codes

UK: 201003
US: C3005
CN: FM01RH0002

This product can be ordered worldwide under the above product codes

 

CAS number

20765-98-4

 

Product Family

Pgm compound solution (aqueous)

 

Process

Catalyst manufacturing

 

Market

Chemicals

 

Benefits

Rhodium chloride solution is air stable.

 

 

 
Rhodium chloride solution
 
 
Application

Rhodium chloride solution is used as a precursor to make heterogeneous and homogeneous catalysts. 

 
Shipping & Handling

Rhodium chloride solution is harmful if swallowed and causes...


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Rhodium(III) chloride solid
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Rhodium chloride solid

Rhodium(III) chloride solid

Chemical Formula

RhCl3

 

Product Codes

UK: 201000
US: C3004D
CN: FM01RH0001

This product can be ordered worldwide under the above product codes

 

CAS number

10049-07-7

 

Product Family

Pgm compound (solid)

 

Process

Catalyst manufacturing

 

Market

Chemicals

 

Benefits

Rhodium chloride solid is air stable and highly soluble in water. It is hygroscopic and contains a mixture of coordinated hydrochloric acid and water.

 
Application

Rhodium chloride solid is used as a precursor to make heterogeneous and homogeneous catalysts.  It is hazardous, so must be handled with appropriate precautions.

 
Shipping & Handling

Rhodium chloride solid may be corrosive to metals.  It is 

harmful if swallowed and causes...
 

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Rhodium sulphate plating solution RJ100S
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Rhodium sulphate plating solution RJ100S

Rhodium sulphate plating solution RJ100S

Chemical Formula

Rh2(SO4)3

 

Product Codes

UK: 153100
US: C3010C
CN: FM01RH0004

This product can be ordered worldwide under the above product codes

 

CAS number

10489-46-0

 

Product Family

Pgm compound solution (aqueous)

 

Process

Electroplating

 

Market

Jewellery, Electronics

 

This sulphate based concentrate has been specifically developed for decorative applications. It will produce bright, white lustrous deposits up to maximum thickness of 2.5 µm.
 
Bath preparation
 
Typical requirements for 1 litre solution Demineralised or distilled water: 800 ml
 
Concentrated sulphuric acid: 20 ml (added cautiously to the water with stirring)
 
RJ100S: 20 ml
 
Metal preparation 
All components must be thoroughly degreased using...
 
trichloroethylene or a similar solvent.
Immediately prior to plating the parts should be immersed in dilute sulphuric acid (5% v/v).


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Rhodium phosphate solution, RJ100P
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Rhodium phosphate plating solution RJ100P

Rhodium phosphate solution, RJ100P

Chemical Formula

RhPO4

 

Product Codes

UK: 153111
US: C3011C

This product can be ordered worldwide under the above product codes

 

CAS number

67859-71-6

 

Product Family

Pgm compound solution (aqueous)

 

Process

Electroplating

 

Market

Jewellery, Electronics

 

This phosphate based concentrate has been specially developed for decorative applications. It will produce bright, white lustrous deposits at thicknesses below 0.5 µm. The recommended maximum thickness is 1 µm.
 
Availability
Available in the following pack sizes:
2 g rhodium content (20 ml)
4 g rhodium content (40 ml)
10 g rhodium content (100 ml)
Other pack sizes can be supplied as required.
 
Bath preparation
Typical requirements for 1 litre solution
Demineralised or distilled water: 800 ml
Concentrated sulphuric acid: 20 ml (added cautiously to the water with stirring)
RJ100P: 20 ml
 
Metal preparation
All components must be thoroughly degreased using...
 

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Hydridocarbonyltris(triphenylphosphino)rhodium(I)
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Rh-42

Hydridocarbonyltris(triphenylphosphino)rhodium(I)

Chemical Formula

(CO)H(PPh3)3Rh

 

Product Codes

UK: 209042
US: C3021

This product can be ordered worldwide under the above product codes

 

CAS number

17185-29-4

 

Product Family

Pgm compound (solid)

 

Process

Hydroformylation

 

Market

Chemicals

 

Benefits
Rh-42 is air stable and contains no halide.

 

Hydridocarbonyltris (triphenylphosphino)rhodium(I)


Application
Rh-42 catalyses hydroformylation reactions. It is normally used with ligands such as...


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Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer
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Rh-120

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer

Chemical Formula

[Rh(Cp*)Cl2]2

 

Product Codes

UK: 209120

This product can be ordered worldwide under the above product codes

 

CAS number

12354-85-7

 

Product Family

Pgm compound (solid)

 

Process

Hydrogenation

 

Market

Chemicals

 

Benefits
Rh-120 is air stable and soluble in organic solvents.
 


Dichloro (pentamethylcyclopentadienyl)  rhodium(III) dimer



Application
Rh-120 catalyses hydrogenation reactions.


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Rh-2EH, 2% Rh
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Rhodium (III) 2-ethyl hexanoate in 2-ethyl hexanol

Rh-2EH, 2% Rh

Chemical Formula

Rh(C6H15O2)3

 

Product Codes

UK: 209006

This product can be ordered worldwide under the above product codes

 

CAS number

20845-92-5

 

Product Family

Pgm compound solution (organic)

 

Process

Hydrosilylation, Hydroformylation

 

Market

Chemicals, Silicones

 

This catalyst is Rh(2-ethylhexanoate)3 in 2-ethylhexanol. It is used for hydrosilylation reactions between vinyl and Si-H groups.
 
Rh-2EH may be used for hydrosilylation reactions where enhanced resistance to poisons is desired. The catalyst supplied dissolved in organic solvent.
 
Benefits
  • High stability rhodium(III) compound
  • Air stable solution
  • Poison resistant with high catalytic activity
Shipping & Handling
Avoid contact with skin and clothing.
Keep container closed.
Use only with...
 

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Rh-2EH, 3.5% Rh
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Rhodium (III) 2-ethyl hexanoate in 2-ethyl hexanol

Rh-2EH, 3.5% Rh

Chemical Formula

Rh(C6H15O2)3

 

Product Codes

UK: 209000

This product can be ordered worldwide under the above product codes

 

CAS number

20845-92-5

 

Product Family

Pgm compound solution (organic)

 

Process

Hydrosilylation, Hydroformylation

 

Market

Chemicals, Silicones

 

This catalyst is Rh(2-ethylhexanoate)3 in 2-ethylhexanol. It is used for hydrosilylation reactions between vinyl and Si-H groups.
 
Rh-2EH may be used for hydrosilylation reactions where enhanced resistance to poisons is desired. The catalyst supplied dissolved in organic solvent.
 
Benefits
  • High stability rhodium(III) compound
  • Air stable solution
  • Poison resistant with high catalytic activity
Shipping & Handling
Avoid contact with skin and clothing
Keep container closed
Use only with...
 

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Rhodium(1,5-cyclooctadiene) chloride dimer
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Rh-93

Rhodium(1,5-cyclooctadiene) chloride dimer

Chemical Formula

[Rh(COD)Cl]2

 

Product Codes

UK: 209093
US: C3024

This product can be ordered worldwide under the above product codes

 

CAS number

12092-47-6

 

Product Family

Pgm compound (solid)

 

Process

Hydrosilylation, Hydrogenation

 

Market

Chemicals, Silicones

 

Benefits
Rh-93 is used to catalyse hydrogenation and hydrosilylation reactions. Rhodium catalysts can be more resistant to poisons than platinum ones for hydrosilylation. It can also be used for isomerisation, hydroformylation, carbonylation, polymerisation and reductive amination.

 

Rhodium(1,5-cyclooctadiene) chloride dimer



Rh-93 is air stable...


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Rhodium(2,4-pentanedionate)(1,5-cyclooctadiene)
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Rh-95, rhodium (acetylacetonato)(1,5-cyclooctadiene)

Rhodium(2,4-pentanedionate)(1,5-cyclooctadiene)

Chemical Formula

Rh(acac)(COD)

 

Product Codes

UK: 209095

This product can be ordered worldwide under the above product codes

 

CAS number

12245-39-5

 

Product Family

Pgm compound (solid)

 

Process

Hydrogenation

 

Market

Chemicals

 

Benefits
Rh-95 is air stable and contains rhodium in oxidation state I, which is catalytically active. It is halide free.
 

Rhodium(2,4-pentanedionate) (1,5-cyclooctadiene)


Application
Rh-95 is used to catalyse hydrogenation reactions. It can also be used as a catalyst precursor for hydroformylation.

Shipping & Handling
Rh-95 causes serious...
 

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Tris(triphenylphosphino)rhodium(I) chloride
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Rh-100, Wilkinson

Tris(triphenylphosphino)rhodium(I) chloride

Chemical Formula

(PPh3)3RhCl

 

Product Codes

UK: 209100
US: C3025S

This product can be ordered worldwide under the above product codes

 

CAS number

14694-95-2

 

Product Family

Pgm compound (solid)

 

Process

Hydrogenation

 

Market

Chemicals

 

Benefits
Rh-100 contains rhodium in oxidation state I, which is catalytically active.


Wilkinson’s catalyst



Application
Rh-100 catalyses hydrogenation reactions. It is slightly air sensitive so must be... 
 

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Rhodium octanoate dimer
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Rh-115

Rhodium octanoate dimer

Chemical Formula

Rh2(C8H15O2)4

 

Product Codes

US: C3027

This product can be ordered worldwide under the above product codes

 

CAS number

73482-96-9

 

Product Family

Pgm compound (solid)

 

Process

Coupling

 

Market

Chemicals

 

Benefits
The product is an air-stable solid that is soluble in most organic solvents.

Rh-115

Application
Rhodium(II) octanoate dimer is used as a homogeneous catalyst for a variety of organic transformations, such as...


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Please contact our Sales Team for SDS and Specifications.

Tris(2,4-pentanedionato)rhodium(III)
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Rh-70, tris(acetylacetonato) rhodium

Tris(2,4-pentanedionato)rhodium(III)

Chemical Formula

Rh(acac)3

 

Product Codes

UK: 200501

This product can be ordered worldwide under the above product codes

 

CAS number

14284-92-5

 

Product Family

Pgm compound (solid)

 

Process

Metal deposition

 

Market

Electronics

 

Benefits
Rh-70 is air stable, contains no halide and has good solubility in organic solvents.

Rh-70

Application

Rh-70 is used to deposit rhodium in processes such as chemical vapour deposition.  It can also be used as a catalyst for hydrosilylation reactions.

Shipping & Handling
Rh-70 is not...


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Rhodium black
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Rhodium black

Rhodium black

Chemical Formula

Rh

 

Product Codes

UK: 200010

This product can be ordered worldwide under the above product codes

 

CAS number

7440-16-6

 

Product Family

Metal powder

 

Process

Electrocatalysis

 

Market

Chemicals

 

Benefits
Rhodium black is a high specific surface area, finely divided powder.
 
Application
Any application requiring finely divided rhodium powder of high catalytic activity.
 

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Rh
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